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个人信息Personal Information
副教授
硕士生导师
电子邮箱：
所在单位：化学与材料工程学院
学历：博士研究生毕业
办公地点：温州大学A区数理学院3C407B室
学位：理学博士学位
毕业院校：清华大学
学科：无机化学
Jian Zhang+, Xi Wu+, Weng-Chon Cheong, Wenxing Chen, Rui Lin, Jia Li, Lirong Zheng, Wensheng Yan, Lin Gu, Chen Chen, Qing Peng, Dingsheng Wang*, Yadong Li*, Cation vacancy stabilization of single-atomic-site Pt1/Ni(OH)x catalyst for diboration of alkynes and alkenes
点击次数：
DOI码：10.1038/s41467-018-03380-z
发表刊物：Nature Communications
摘要：Development of single-atomic-site catalysts with high metal loading is highly desirable but proved to be very challenging. Although utilizing defects on supports to stabilize independent metal atoms has become a powerful method to fabricate single-atomic-site catalysts, little attention has been devoted to cation vacancy defects. Here we report a nickel hydroxide nanoboard with abundant Ni(2+) vacancy defects serving as the practical support to achieve a single-atomic-site Pt catalyst (Pt1/Ni(OH)x) containing Pt up to 2.3 wt% just by a simple wet impregnation method. The Ni(2+) vacancies are found to have strong stabilizing effect of single-atomic Pt species, which is determined by X-ray absorption spectrometry analyses and density functional theory calculations. This Pt1/Ni(OH)x catalyst shows a high catalytic efficiency in diboration of a variety of alkynes and alkenes, yielding an overall turnover frequency value upon reaction completion for phenylacetylene of ~3000 h(-1), which is much higher than other reported heterogeneous catalysts.
论文类型：期刊论文
学科门类：理学
文献类型：J
卷号：9
页面范围：1002
是否译文：否
发表时间：2018-03-10
收录刊物：SCI
发布期刊链接：https://www.nature.com/articles/s41467-018-03380-z
上一条：Weng-Chon Cheong+, Wenjuan Yang+, Jian Zhang+, Yang Li, Di Zhao, Shoujie Liu, Konglin Wu, Qinggang Liu, Chao Zhang, Dingsheng Wang, Qing Peng, Chen Chen*, Yadong Li*, Isolated Iron Single-Atomic Site-Catalyzed Chemoselective Transfer Hydrogenation of Nitroarenes to Arylamines
下一条：Qingquan Lu+, Jian Zhang+, Pan Peng, Guanghui Zhang, Zhiliang Huang, Hong Yi, Jeffrey T Miller, Aiwen Lei*, Operando X-ray absorption and EPR evidence for a single electron redox process in copper catalysis