As the core of contemporary fine chemical industry, organic synthetic chemistry plays an important role in the development of materials science, pesticide science and pharmaceutical science. Thermocatalytic and electrocatalytic technologies are currently the main technologies to achieve efficient organic reactions, and the widely used homogeneous catalysts in these technologies suffer from the hard separation and recovery. The use of heterogeneous catalysts to achieve the heterogenization of organic reactions can effectively reduce production costs and product purification difficulties, which is considered to meet the requirements of modern fine chemical production and green chemistry. Our group has been focusing on the development of heterogeneous catalysts with performance comparable to that of homogeneous catalysts to achieve efficient thermocatalytic and electrocatalytic organic reactions.