钱金杰
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发表刊物:CrystEngComm
项目来源:国家自然科学基金项目
关键字:AlOF-1.4CO2; GaOF-1.4CO2; InOF-1.4CO2
摘要:The theoretically optimal adsorption locations in hydroxyl (OH)-decorated metal–organic frameworks show that the captured carbon dioxide (CO2) molecules interact with the cis-μ2-OH groups in an end-on mode, which shows a moderate to weak hydrogen bond. The experimental isotherms and ideal adsorption solution theory (IAST) calculations show the high selectivity of CO2 for nitrogen at 273, 283 and 295 K and 1.0 bar for three types of OH-appended isostructures.
第一作者:钱金杰
通讯作者:钱金杰
卷号:19
ISSN号:1466-8033
是否译文:否
CN号:10.1039/C7CE01195D
发表时间:2017-08-17