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Preparation, Structures and Magnetic Properties of Two Co-based Clusters with Triangular Core and Cuboidal Core Geometries

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Journal:Chinese Journal of Structural Chemistry
Funded by:国家自然科学基金项目
Key Words:Co-based clusters; triangular core; cuboidal core; magnetic property
Abstract:Two novel Co-based clusters with the 2-(hydroxylmethyl) pyridine (hmpH) ligand, formulated as [Co3(hmp)6(hmpH)].2NO3.3H2O (ZTU-3) and [Co4(hmp)4(CH3CO2)2(H2O)4].2NO3 (ZTU-4), have been successfully synthesized and structurally characterized. ZTU-3 features a triangular core geometry, while ZTU-4 exhibits a cuboidal core geometry. In addition, the magnetic properties of ZTU-3 and ZTU-4 are also all investigated.
First Author:QJJ
Correspondence Author:钱金杰
Volume:38
ISSN No.:0254-5861
Translation or Not:no
CN No.:10.14102/j.cnki.0254–5861.2011–2338
Date of Publication:2019-10-30

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