A microporous europium–organic framework anchored with open –COOH groups for selective cation sensing
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Journal:CrystEngComm Funded by:国家自然科学基金项目 Abstract:[Eu2(BPTC)(H2BPTC)(DMF)4]·Guest (BMM-7) is a new 3-dimensional microporous metal–organic framework based on a functional [Eu2(COO)6(DMF)2] secondary building unit, which is rendered with uncoordinated carboxylate groups protruding into the channels. The microporous nature is confirmed using nitrogen isotherms at 77 Kelvin and the open –COOH groups can effectively and selectively capture Cu(II) cations in the exchange process. First Author:QJJ Correspondence Author:钱金杰 Volume:18 ISSN No.:1466-8033 Translation or Not:no CN No.:10.1039/C6CE01801G Date of Publication:2016-09-19 -
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