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Sorption Behavior and Magnetic Properties of A Heterometallic Organic Framework with Octahedral Cages and One-Dimensional Channels

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Journal:Zeitschrift für anorganische und allgemeine Chemie
Funded by:省、市、自治区科技项目
Abstract:The ZnII-CoII organic framework [Me2NH2][Zn2Co(μ3-OH)(BTC)2(H2O)]·2H2O (FJI-6) (H3BTC = 1, 3,5-benzenetricarboxylic acid and DMA = N.N′-dimethyl acetamide), was synthesized and structurally characterized. FJI-6 shows a three-dimensional heterometallic microporous framework with coexisting octahedral cages and one-dimensional channels assembled by Zn2Co(μ3-OH)(CO2)6 secondary building units. In addition, the sorption behavior and magnetic properties of FJI-6 were investigated.
First Author:QJJ
Correspondence Author:钱金杰
Volume:7
ISSN No.:0044-2313
Translation or Not:no
CN No.:DOI: 10.1002/zaac.201600033
Date of Publication:2016-04-15

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